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Text from PDF Page: 001STANDARD HYDROGEN ELECTRODE A standard hydrogen electrode (SHE) consists of a platinised platinum electrode immersed in a solution of 1 mol dm-3 H+ ions. Hydrogen gas at a pressure of 1 atm and 25 oC is bubbled over the platinum electrode. 2 H+ (aq) + 2 e− H2 (g) The platinum electrode has a large surface area so that it can establish an equilibrium between H2(g) and H+ (aq) as rapidly as possible.
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