Kinetics of Electrode Reactions

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Kinetics of Electrode Reactions ( kinetics-electrode-reactions )

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Chapter 3: Kinetics of Electrode Reactions Goal: To understand the observed behavior of electrode kinetics with respect to potential and concentration. υ= i/nFA (mol/s-cm2) Rate = f(E) Dynamic Equilibrium kf B kb A υf = kfCA (M/s) s-1 υb = kbCB υnet = kfCA - kbCB kf/kb = Keq = CB/CA Non-zero rates but equal. Kinetics describe the evolution of mass flow throughout the system, including the approach to equilibrium and the dynamic maintenance of the state.

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